Tracers / [68Ga]Ga-DOTA-TOC

[68Ga]Ga-DOTA-TOC

Also written as [68Ga]DOTATOC; [68Ga]Ga-DOTA-TOC; [68Ga]Ga-DOTATOC; [Ga-68]DOTATOC; [Ga-68]Ga-DOTA-TOC; [Ga-68]Ga-DOTATOC; DOTA-TOC
Radionuclide
Ga-68 t½ 67.71 min
Modality
PET
Production route
Stage
Approved
Syntheses indexed
86

What it is

Compound class
Radiolabelled somatostatin analogue peptide (octreotide/DOTA-Tyr3-octreotide derivative)
Target / mechanism
Somatostatin receptor, predominantly subtype 2 (SSTR2) PMID 29243585
Clinical application
PET imaging of somatostatin-receptor-expressing neuroendocrine tumours (NET) PMID 29243585
Theranostic pair
<a href="/tracers/lu177-dotatoc/">lu177-dotatoc</a>

Regulatory status

FDA
2019, Gallium Ga 68 Edotreotide Injection, University of Iowa Health Care (UIHC) PET Imaging FDA (Drugs@FDA/openFDA): NDA210828, approved 2019-08-21
EMA (centralised)
2016, SomaKit TOC, Advanced Accelerator Applications (Novartis group) EMA medicines register export (2026-09-09): EMEA/H/C/004140, 'Authorised'; date of authorisation 8 Dec 2016 (EMA EPAR overview)
Other approvals
Brand names
Gallium Ga 68 Edotreotide (US); SomaKit TOC (EU)

Clinical use

Typical injected activity
Uptake time

Reported in the literature. Not a dosing recommendation.

Published syntheses

ModuleCassettePurificationYield %RCP %Precursor / supplierSource
iMiDEV
PMB-Alcen
vendor cassetteSPE46 ± 7
yes
99.6 ± 0.2% (HPLC)DOTA-TOC
MedChemTronica, Sollentuna, Sweden
38091157
2023 EJNMMI Radiopharm Chem
Microfluidic-based production of [68Ga]Ga-FAPI-46 and [68Ga]Ga-DOTA-TOC using the cassette-based iMiDEV™ microfluidic radiosynthesizer — For [68Ga]Ga-DOTA-TOC, RCYdc was 46 ± 7% (n = 3)
Scintomics GRP / GRP-3V
Scintomics
SPEDOTATOC
ABX
32410136
2020 EJNMMI Radiopharm Chem
The syntheses were performed using a GRP® synthesis module from Scintomics (Fürstenfeldbruck, Germany) with the cationic concentration protocol provided by Scintomics.
Modular-Lab PharmTracer
Eckert & Ziegler
vendor cassetteSPE64%>95%DOTATOC
ABX
34439784
2021 Biomolecules
Automated radiosynthesis was performed on an Eckert & Ziegler Modular-Lab PharmTracer synthesis module using the Modular-Lab software (Eckert & Ziegler). — RCYs of 57% and 64% were obtained for [68Ga]Ga-FAPI-46 and [68Ga]Ga-DOTATOC, respectively.
FASTlab
GE HealthCare
SPE54.03±2.45
yes
97.86±0.51DOTATOC
BCN Peptides, Barcelona, Spain
25369268
2014 PLoS One
Most of the synthesis was performed using an automated process programmed in a FastLab module (General Electric Healthcare). — the decay-corrected radiochemical yield (%) was 54.03±2.45, 66.13±3.35 and 67.81±3.12
28529632
2017 Theranostics
Scintomics (model not stated)
Scintomics
26843617
2016 Oncotarget
[68Ga]DOTATOC was prepared using a modification of the method described by Breeman et al. [24] using a SCINTOMICS radiotracer synthesis module (Scintomics, Fürstenfeldbruck, Germany).
Scintomics GRP / GRP-3V
Scintomics
vendor cassetteSPE82.2 ± 2.7%
yes
97.3 ± 0.0%DOTATOC (Edotreotide)
MedChemExpress
41011146
2025 Pharmaceuticals (Basel)
A Scintomics GRP-3V module (Scintomics, Fürstenfeldbruck, Germany) was used for the automated synthesis of [68Ga]Ga-DOTATOC in combination with a 2-bench cassette system — an average decay-corrected yield (d.c.y.) of 82.2 ± 2.7% based on the theoretical maximum gallium-68 activity of the generator at that time point
Scintomics GRP / GRP-3V
Scintomics
vendor cassetteSPE88.3 ± 0.6%
yes
97.8 ± 1.3%DOTATOC (Edotreotide)
MedChemExpress
41011146
2025 Pharmaceuticals (Basel)
A Scintomics GRP-3V module (Scintomics, Fürstenfeldbruck, Germany) was used for the automated synthesis of [68Ga]Ga-DOTATOC in combination with a 2-bench cassette system — corresponding to an average decay-corrected yield of 88.3 ± 0.6%
SPE34.4 ± 21.3% (0.6 nmol)
yes
DOTATOC
Bachem, Bubendorf, Switzerland
22682112
2012 EJNMMI Res
34294854
2021 Sci Rep
FASTlab 2
GE HealthCare
custom manifoldHPLC48.9
yes
97.98Ga-DOTATOC acetate
ABX
40353471
2025 Curr Radiopharm
the synthesis of [68Ga]Ga-DOTA-TOC was performed by FASTlab2 developer system — achieving a synthesis yield percentage (corrected for decay) of an average value of 48.9%
Kit-based preparation
Advanced Accelerator Applications
vendor cassetteedotreotide (Somakit TOC)
Advance Accelerator Applications, Italy
40353471
2025 Curr Radiopharm
5 mL of [68Ga]GaCl3 was eluted through metal-free materials into a Somakit TOC® (40 mg of edotreotide) vial (Advance Accelerator Applications, Italy)
iQS-TS
ITG (Isotope Technologies Garching)
vendor cassetteSPE62.699.1DOTATOC34658552
2021 Indian J Nucl Med
Hot cell to house 68Ga iQS-TS Synthesis module, ITG, Germany — The average % synthesis yield and average % radiochemical purity obtained over all the synthesis were 62.6 (±2.3) and 99.1 (±0.2) %, respectively
42591815
2026 Gland Surg
Kit-based preparation
Novartis
vendor cassette98.9 ± 0.7% by rTLC; 93.1 ± 1.4% by rHPLCedotreotide
Novartis
42344682
2026 World J Nucl Med
Radiolabeling experiments were conducted using commercial SOMAKIT-TOC (edotreotide) kits.
Kit-based preparation
Novartis
vendor cassette98.9 ± 1.1% by rTLC; 91.6 ± 1.0% by rHPLCedotreotide
Novartis
42344682
2026 World J Nucl Med
a full kit vial was reconstituted with 2 mL of WFI... two 68 Ge/ 68 Ga generators were connected to the kit vial and eluted sequentially, directly into the vial
Kit-based preparation
Novartis
vendor cassetteAliquot1: 99.0 ± 0.6% rTLC, 91.1 ± 3.4% rHPLC; Aliquot2: 97.6 ± 0.9% rTLC, 90.8 ± 2.3% rHPLCedotreotide
Novartis
42344682
2026 World J Nucl Med
a kit vial was reconstituted with 6.2 mL of WFI... to obtain two equal aliquots. The first radiolabeling was performed immediately on one aliquot, following the steps described in Procedure 1.
Kit-based preparation
Novartis
vendor cassetteAliquot1: 95.6 ± 1.4% rTLC, 87.2 ± 3.4% rHPLC; Aliquot2: 97.2 ± 3.4% rTLC, 89.6 ± 3.0% rHPLCedotreotide
Novartis
42344682
2026 World J Nucl Med
the kit vial was reconstituted and divided into two aliquots as described in Procedure 3. Both aliquots were then radiolabeled on the same day... using the two-generator preparation method detailed in Procedure 2.
42141279
2026 Eur J Nucl Med Mol Imaging
42048552
2026 Eur Heart J Cardiovasc Imaging
41894844
2026 Endocrinol Diabetes Metab Case Rep
41886137
2026 Curr Treat Options Oncol
Scintomics GRP / GRP-3Vvendor cassetteSPE62>98% for 68Ga-DOTATOCDOTA0-(Phe1-Tyr3)-octreotide41824275
2026 EJNMMI Radiopharm Chem
an automated synthesis module (Scintomics GRP®, Fürstenfeldbruck, Germany) — assuming a reference radiolabelling yield of 62%
41693498
2026 Nucl Med Commun
41210494
2025 Front Endocrinol (Lausanne)
Scintomics GRP / GRP-3V
Scintomics
vendor cassetteSPE82.2 ± 2.7%
yes
97.3 ± 0.0%DOTATOC (Edotreotide)
MedChemExpress
41011146
2025 Pharmaceuticals (Basel)
A Scintomics GRP-3V module (Scintomics, Fürstenfeldbruck, Germany) was used for the automated synthesis of [68Ga]Ga-DOTATOC — average decay-corrected yield (d.c.y.) of 82.2 ± 2.7%
Scintomics GRP / GRP-3V
Scintomics
vendor cassetteSPE88.3 ± 0.6%
yes
97.8 ± 1.3%DOTATOC (Edotreotide)
MedChemExpress
41011146
2025 Pharmaceuticals (Basel)
A Scintomics GRP-3V module (Scintomics, Fürstenfeldbruck, Germany) was used for the automated synthesis of [68Ga]Ga-DOTATOC — corresponding to an average decay-corrected yield of 88.3 ± 0.6%
Manual synthesisSPE60.81 ± 1.96%>97%DOTATOC acetate (precursor D) / DOTATOC acetate salt (precursor E)
ABX
40941986
2025 Molecules
DOTA-TOC precursor in 1 mL acetate buffer was added to a vial containing about 5 mL of gallium-68 chloride. The reaction mixture was placed in a heating block preheated to 95 °C and heated for 10 min. — The obtained yields were 60.81 ± 1.96% for the first precursor and 54.15 ± 0.40% for the second
Kit-based preparation
Novartis
vendor cassettenone54.15 ± 0.40%>97%SomaKit TOC
Novartis
40941986
2025 Molecules
The labeling procedure of the precursor F was performed according to the standard kit manufacturer’s instruction. — The obtained yields were 60.81 ± 1.96% for the first precursor and 54.15 ± 0.40% for the second
40598690
2025 Cancer Imaging
40455253
2025 Eur J Nucl Med Mol Imaging
40453587
2025 Front Endocrinol (Lausanne)
40445313
2025 Eur J Nucl Med Mol Imaging
40361414
2025 Cancers (Basel)
miniAllinOne
Trasis
vendor cassette99.21%EDOTREOTIDE (DOTA-TOC)
Advanced Accelerator Applications, Rueil-Malmaison, France
40358768
2025 EJNMMI Radiopharm Chem
Radiolabeling was carried out using the automated synthesizer MiniAiO® (Trasis SA, Ans, Belgique)
FASTlab 2
GE HealthCare
custom manifoldHPLC48.9
yes
97.98Ga-DOTATOC acetate
ABX
40353471
2025 Curr Radiopharm
the synthesis of [68Ga]Ga-DOTA-TOC was performed by FASTlab2 developer system according to the Guidelines on Good Radiopharmacy Practice (cGRPP) — with a decay-corrected yield (time of synthesis: 40 minutes) from an average minimum of 45.1% to a maximum of 52.5% (Mean: 48.9%)
Kit-based preparation
Advanced Accelerator Applications
Somakit TOC (edotreotide)
Advance Accelerator Applications, Italy
40353471
2025 Curr Radiopharm
Following the Somakit TOC® SmPC (Summary of Product Characteristics), 5 mL of [68Ga]GaCl3 was eluted through metal-free materials into a Somakit TOC® (40 mg of edotreotide) vial (Advance Accelerator Applications, Italy)
39878896
2025 Eur J Nucl Med Mol Imaging
FASTlab 2
GE HealthCare
custom manifoldnone97.81DOTA-(Tyr3)-octreotide acetate (DOTA-TOC)
Fischer Scientific
39598846
2024 Molecules
Automated labeling of the precursor was accomplished using a FASTLab 2 synthesizer.
39579473
2024 Endocr Connect
39538188
2024 BMC Endocr Disord
Modular-Lab PharmTracer
Eckert & Ziegler
vendor cassetteDOTA-TOC
piCHEM, Raaba-Grambach, Austria
39464654
2024 Front Nucl Med
[68Ga]Ga-DOTA-TOC was synthesized in an automatic Modular-Lab Pharm Tracer module connected to a 68Ge/68Ga-generator IGG100 (Eckert & Ziegler), following the synthesis template and kit reagents of the manufacturer.
DOTATOC39142827
2024 J Nucl Med
38788146
2024 Arch Endocrinol Metab
38697682
2024 BMJ Case Rep
Manual synthesisSPE78 ± 15%>99%DOTA-TOC38675474
2024 Pharmaceuticals (Basel)
[68Ga]Ga-DOTA-TOC was synthesized with slight modifications of the described production method [32,33]. — Radiochemical yield was 78 ± 15% (n = 5)
38403723
2024 Eur J Nucl Med Mol Imaging
Manual synthesisSPEDOTA-TOC38346097
2024 J Med Chem
Identical procedures were used to synthesize 68Ga-DOTA-TOC as the positive control.
iMiDEV
PMB-Alcen
vendor cassetteSPE46 ± 7%
yes
99.6 ± 0.2% (HPLC)DOTA-TOC
MedChemTronica, Sollentuna, Sweden
38091157
2023 EJNMMI Radiopharm Chem
Microfluidic cassette-based iMiDEV™ radiosynthesizer — For [68Ga]Ga-DOTA-TOC, RCYdc was 46 ± 7% (n = 3)
37767685
2023 Endocrinol Diabetes Metab Case Rep
36354685
2022 Curr Issues Mol Biol
Scintomics GRP / GRP-3V
Scintomics
vendor cassetteSPEDOTATOC
ABX
35889351
2022 Molecules
the automated synthesis module Scintomics GRPTM (Scintomics GmbH, Fürstenfeldbruck, Germany)
Modular-Lab PharmTracer
Eckert & Ziegler
vendor cassette34822040
2021 EJNMMI Res
68Ga-DOTATOC was produced using an automated synthesis platform (Modular PharmLab, Eckert & Ziegler, Germany) equipped with a disposable cassette system (C4-Ga68-PP).
Kit-based preparation
Advanced Accelerator Applications
vendor cassette98.82%DOTATOC
Advanced Accelerator Applications
32188715
2020 ESMO Open
68Ga-DOTATOC was prepared on the day of the administration using as the reaction vial containing a lyophilised formulation of 40 µg of DOTATOC (vial 1) to be radiolabelled with 68GaCl3
Manual synthesisnone>95%DOTA-TOC
ABX
31123943
2019 EJNMMI Res
A solution of 68Ga(OAc)3 in acetate buffer was added to 20 nmol of each peptide. The reaction mixture was shaken for 10 min at 80 °C to afford [68Ga]Ga-DOTA-TOC or at 20 °C for 10 min to afford [68Ga]Ga-DATA-TOC.
30510849
2018 Am J Nucl Med Mol Imaging
Manual synthesisHPLC+SPE61%
yes
>98%DOTATOC
In-house / non-commercial (various)
29503845
2017 EJNMMI Radiopharm Chem
heated in a microwave oven (catalog number: DMW7700WDB, Danby Appliance, Findlay, Ohio) — 61 ± 5, 62 ± 8 and 68 ± 13% respectively, n = 3
Scintomics (model not stated)
Scintomics
26843617
2016 Oncotarget
[68Ga]DOTATOC was prepared using a modification of the method described by Breeman et al. [24] using a SCINTOMICS radiotracer synthesis module (Scintomics, Fürstenfeldbruck, Germany).
FASTlab
GE HealthCare
SPE54.03
yes
97.86DOTATOC
BCN Peptides, Barcelona, Spain
25369268
2014 PLoS One
Most of the synthesis was performed using an automated process programmed in a FastLab module (General Electric Healthcare). — the decay-corrected radiochemical yield (%) was 54.03±2.45, 66.13±3.35 and 67.81±3.12
Scintomics (model not stated)
Scintomics
24742330
2014 BMC Cancer
68Ga-DOTATOC/68Ga-DOTATATE was prepared using a modification of the method described by Breeman et al. [25] using a radiotracer synthesis module (Scintomics, Fürstenfeldbruck, Germany).
23522791
2013 Appl Radiat Isot
HPLC64.6898 ± 0.22%DOTATOC35190517
2022 Nucl Med Commun
nonegreater than 80%DOTATOC22755505
2012 Bioconjug Chem
The NaCl method was further evaluated using an automated fluid handling system — radiochemical yields greater than 80%
nonein excess of 65%greater than 99%DOTATOC22755505
2012 Bioconjug Chem
The NaCl method was further evaluated using an automated fluid handling system and it routinely facilitates radiochemical yields in excess of 65% in less than 15 min, with radiochemical purity consistently greater than 99% for the preparation of (68)Ga-DOTATOC. — routinely facilitates radiochemical yields in excess of 65% in less than 15 min
22336375
2012 Nucl Med Biol
SPEabout 60%
yes
DOTA-Tyr-octreotide (DOTATOC)17901771
2007 Nucl Med Commun
A fully automated radiopharmaceutical synthesis device based on a modular concept for remote-controlled processing was developed and evaluated for a number of DOTA-derivatized peptides. — Automated synthesis resulted in overall decay-corrected reaction yields of about 60% within 10 min.
DOTA-TOC31845408
2020 J Labelled Comp Radiopharm
utilizing a cassette module (GAIA; Elysia-Raytest; Germany) with a manual setup
DOTA-TOC31845408
2020 J Labelled Comp Radiopharm
manual setup for routine clinical production
Somakit TOC30636620
2019 Curr Radiopharm
Development of a labeling process using a synthesizer is particularly interesting for the quality and reproducibility of the final product
Somakit TOC30636620
2019 Curr Radiopharm
Somakit TOC® is a radiopharmaceutical kit registered in the European Union for the preparation of [68Ga]Ga-DOTA-TOC
Somakit TOC30636620
2019 Curr Radiopharm
28±0.5 minutes for the semi-automated
SPE54.4 ± 2.3 %96.94 ± 0.74 %DOTA-TOC29745348
2018 Curr Radiopharm
We reported the [68Ga]Ga-DOTA-TOC production by automated cassette-based theranostic synthesizer system used in combination with a disposable GMP grade cassette system for cationic purification. — The average synthesis yield of radiopharmaceutical production was 54.4 ± 2.3 % and the radiochemical purity average was found 96.94 ± 0.74 %.
>80%>98%DOTATOC27103024
2016 J Nucl Med
the generator system is contained within the fluidic labeling module — greater than 80% radiochemical yield
42554825
2026 Eur J Nucl Med Mol Imaging
42350034
2026 J Nucl Med
42257554
2026 Clin Nucl Med
41699279
2026 Eur J Nucl Med Mol Imaging
34740949
2022 J Nucl Med
32149792
2020 Clin Nucl Med
31806775
2020 J Nucl Med
31764593
2020 Nucl Med Commun
31520872
2019 Nucl Med Biol
31302632
2020 J Nucl Med
29191855
2018 J Nucl Med
23370092
2013 Q J Nucl Med Mol Imaging
23151915
2013 Eur J Nucl Med Mol Imaging

Precursor

Common precursor
DOTA-TOC PMID 38091157 (DOI 10.1186/s41181-023-00229-9)
Suppliers seen in the literature
MedChemTronica (Sollentuna, Sweden)
Cited suppliers in indexed syntheses
ABX, Advance Accelerator Applications, Advanced Accelerator Applications, Advanced Accelerator Applications, Rueil-Malmaison, BCN Peptides, Bachem, Bubendorf, Fischer Scientific, In-house / non-commercial (various), MedChemExpress, MedChemTronica, Sollentuna, Novartis, piCHEM
Typical final purification
SPE

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Quality control Pharmacopoeial monograph

Ph. Eur. monograph
2482
USP monograph
not verified — the USP-NF monograph index is subscription-only and no public confirmation was found
AppearancepHRCP HPLCRCP TLCHPLC UVRadionuclidic (HPGe)Half-lifeActivityEndotoxins (LAL)SterilityFilter integrityMolar activityMetal impuritiesGe-68 breakthrough
How this set was arrived at. Base set per Ph. Eur. 0125 + monograph 2482. Ge-68 breakthrough + metal impurities: generator Ga-68 only. RECOMMEND ADD: molar activity / peptide content (saturable target).

Tests listed by reference only. Monograph texts are copyrighted and are not reproduced here. How these are derived

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Notes

Added from reverse module search (stage 6); 26 article(s) with Ga-68. Also seen with Cu-61[1], Ga-67[1], Tb-161[1], Y-90[1] (too few articles for own row).