Tracers / [18F]FES

[18F]FES

Also written as [18F]FES; [18F]Fluoroestradiol; [F-18]FES; [F-18]Fluoroestradiol; F-18 FES; F-18 Fluoroestradiol; FES
Radionuclide
F-18 t½ 109.77 min
Modality
PET
Production route
Stage
Approved
Syntheses indexed
7

What it is

Compound class
Radiolabelled estradiol analogue (16α-[18F]fluoro-17β-estradiol)
Target / mechanism
Estrogen receptor (ER) — binding affinity comparable to endogenous estradiol PMID 17920354
Clinical application
PET imaging adjunct for detecting ER-positive lesions in patients with recurrent or metastatic breast cancer FDA label NDA212155
Theranostic pair

Regulatory status

FDA
2020, Cerianna, GE Healthcare FDA (Drugs@FDA/openFDA): NDA212155, approved 2020-05-20
EMA (centralised)
No EMA medicines register export (2026-09-09): no 'fluoroestradiol' entry
Other approvals
Brand names
Cerianna

Clinical use

Typical injected activity
Uptake time

Reported in the literature. Not a dosing recommendation.

Published syntheses

ModuleCassettePurificationYield %RCP %Precursor / supplierSource
Modular-Lab (model not stated)
Eckert & Ziegler
custom manifoldHPLC40.0 ± 5.0%
yes
>97%MMSE (3-methoxymethyl-16β, 17β-epiestriol-O-cyclic sulfone)
ABX
23762549
2013 Int J Mol Imaging
the E & Z Modular Lab synthesizer — The decay-corrected radiochemical yield for the qualification runs was 40.0 ± 5.0% (N = 12).
Manual synthesisestradiol precursor41515390
2025 Molecules
It is produced via automated fluorination of an estradiol precursor at the C16 position using [18F] from a cyclotron, under strictly controlled conditions to ensure high radiochemical purity and preserved biological activity.
HPLC29520821
2018 J Labelled Comp Radiopharm
HPLC>99%17718929
2007 J Pharm Pharm Sci
SPE40%-45%
no
35996821
2022 J Labelled Comp Radiopharm
the Synthra RNplus research automated platform — the yield was considerably improved (40%-45% ndc)
HPLC+SPE30-35%
yes
>99%cyclic sulfate precursor32174461
2020 Appl Radiat Isot
our home-built automated multi-purpose 18F-radiosynthesis module — the radiochemical yield was 30-35% decay corrected to end of bombardment (EOB), based on H[18F]F
HPLC50 ± 2.35%
yes
96.1 ± 0.3%22044863
2012 Nucl Med Commun
using a TRACERlab FXFN module — the decay-corrected radiochemical yield of [¹⁸F]FES was 50 ± 2.35% (n=4)

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Quality control Preliminary — inferred from compound class

Ph. Eur. monograph
USP monograph
AppearancepHRCP HPLCRCP TLCHPLC UVRadionuclidic (HPGe)Half-lifeActivityEndotoxins (LAL)SterilityFilter integrity
How this set was arrived at. base set per Ph. Eur. general monograph 0125 (rule); organic-phase radiosynthesis assumed from isotope/compound class, no synthesis data confirming it -> GC residual solvents (preliminary); conventional nucleophilic 18F-fluorination assumed from isotope/compound class, no synthesis data confirming K222 use -> Kryptofix test (preliminary)

Tests listed by reference only. Monograph texts are copyrighted and are not reproduced here. How these are derived

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Notes

Added from reverse module search (stage 6); 9 article(s) with F-18.