Tracers / [18F]FAZA

[18F]FAZA

Also written as [18F]FAZA; [18F]fluoroazomycinarabinoside; [F-18]FAZA; [F-18]fluoroazomycinarabinoside; F-18 FAZA; FAZA
Radionuclide
F-18 t½ 109.77 min
Modality
PET
Production route
Stage
Syntheses indexed
4

What it is

Compound class
Radiolabelled 2-nitroimidazole (azomycin arabinoside derivative)
Target / mechanism
Hypoxic cells — bioreductive (nitroreductase-mediated) trapping under low oxygen tension PMID 15632040
Clinical application
Tumour-hypoxia PET imaging (head and neck, lung, prostate, rectal cancers) PMID 24152663
Theranostic pair

Regulatory status

FDA
EMA (centralised)
Other approvals
Brand names

Clinical use

Typical injected activity
Uptake time

Reported in the literature. Not a dosing recommendation.

Published syntheses

ModuleCassettePurificationYield %RCP %Precursor / supplierSource
TRACERlab FX FN
GE HealthCare
custom manifoldHPLC4.8%
no
FAZA precursor
Prof. Friedrich Hammerschmidt (Universität Wien, Austria) and Prof. Hans-Jürgen Machulla, Steinbeis Transfer Center Radiopharmacy, Germany
21769163
2011 J Labelled Comp Radiopharm
the Tracerlab synthesis module was used in the original "out-of-the-box" configuration illustrated in Figure 3 — Typical yield of [18F]FAZA prepared using this method is 4.8% (non-decay corrected, n = 25).
70-90%21989864
2012 Nuklearmedizin
SPE21.98±1.40%
no
>95%1-(2,3-di-O-acetyl-5-O-tosyl-alpha-D-arabinofuranosyl)-2-nitroimidazole20478712
2010 Appl Radiat Isot
[(18)F]FAZA was prepared via a one-pot, two-step synthesis using a nuclear interface nucleophilic synthesis module. — The overall radiochemical yield obtained was 21.98+/-1.40% (n=5, without decay correction)
52.4±5.3%
yes
2.5mg (5.2 μmol) of the precursor21420304
2011 Appl Radiat Isot
a modified NIRS original synthesis system for clinical use — a high radiochemical yield of 52.4±5.3% (decay-corrected, n=8)

Precursor

Common precursor
FAZA precursor PMID 21769163 (DOI 10.1002/jlcr.1865)
Suppliers seen in the literature
academic (Univ. Wien / Steinbeis Transfer Center Radiopharmacy)
Cited suppliers in indexed syntheses
Prof. Friedrich Hammerschmidt (Universität Wien, Austria) and Prof. Hans-Jürgen Machulla
Typical final purification
HPLC (semi-preparative)

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Quality control Preliminary — inferred from compound class

Ph. Eur. monograph
USP monograph
AppearancepHRCP HPLCRCP TLCHPLC UVResidual solvents (GC)Radionuclidic (HPGe)Half-lifeActivityEndotoxins (LAL)SterilityFilter integrity
How this set was arrived at. base set per Ph. Eur. general monograph 0125 (rule); organic solvent confirmed in synthesis data (PMID 21769163) -> GC residual solvents; conventional nucleophilic 18F-fluorination assumed from isotope/compound class, no synthesis data confirming K222 use -> Kryptofix test (preliminary)

Tests listed by reference only. Monograph texts are copyrighted and are not reproduced here. How these are derived

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Notes

Added from reverse module search (stage 6); 7 article(s) with F-18.