Tracers / [18F]FTHA

[18F]FTHA

Also written as [18F]fluoro-6-thia-heptadecanoic; [18F]FTHA; [F-18]fluoro-6-thia-heptadecanoic; [F-18]FTHA
Radionuclide
F-18 t½ 109.77 min
Modality
PET
Production route
Stage
Syntheses indexed
4

What it is

Compound class
fluorinated thia fatty acid analog (radiolabeled fatty acid, tosylate-derived thia-heptadecanoate precursor)
Target / mechanism
Clinical application
Imaging of fatty acid circulation/lipid metabolism by PET PMID 38543104
Theranostic pair

Regulatory status

FDA
EMA (centralised)
Other approvals
Brand names

Clinical use

Typical injected activity
Uptake time

Reported in the literature. Not a dosing recommendation.

Published syntheses

ModuleCassettePurificationYield %RCP %Precursor / supplierSource
TRACERlab FX N ProHPLC+SPE10.9±2.2 %
no
<93.5 %benzyl-14-(R,S)-tosyloxy-6-thiaheptadecanoate
ABX
31759313
2020 Nucl Med Biol
All the syntheses were optimized in an automated TRACERlab FX-N Pro synthesizer. — for [18F]FTHA the uncorrected yield was 10.9±2.2 %
fixed tubingHPLC+SPE5.52 ± 2.38%>95%Benzyl-14-(R,S)-tosyloxy-6-thiaheptadecanoate38543104
2024 Pharmaceuticals (Basel)
a former 11C-methylation vessel-based PET synthesizer (formerly Nuclear Interface, now General Electric Medical Systems, Uppsala, Sweden) was used. — a radiochemical yield (RCY) of 5.52 ± 2.38% (0.23–4.56 GBq) at the end of the synthesis (EOS)
ELIXYS FLEX/CHEM
Sofie Biosciences
vendor cassetteHPLC+SPE13.01 ± 5.63%>95%Benzyl-14-(R,S)-tosyloxy-6-thiaheptadecanoate38543104
2024 Pharmaceuticals (Basel)
Radiochemical production was performed on the Elixys Flex/Chem (Sofie Biosciences, Dulles, VA, USA), a commercially available automated disposable cassette-based radiosynthesizer. Purification and formulation were performed on the commercially available automated unit, Pure/Form (Sofie Biosciences). — a significantly increased RCY of 13.01 ± 5.63% (1.60–6.27 GBq) at the EOS starting from 19–26 GBq (Table 1)
HPLC+SPE13% ± 6.3%
yes
29205456
2018 J Labelled Comp Radiopharm
An automated synthesis device was constructed in-house for multistep nucleophilic 18 F-fluorination and a control system was developed. — The radiochemical yield of 14-(R,S)-[18 F]fluoro-6-thia-heptadecanoic acid, decay-corrected to the end of bombardment, was 13% ± 6.3%.

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Quality control Preliminary — inferred from compound class

Ph. Eur. monograph
USP monograph
AppearancepHRCP HPLCRCP TLCHPLC UVRadionuclidic (HPGe)Half-lifeActivityEndotoxins (LAL)SterilityFilter integrity
How this set was arrived at. base set per Ph. Eur. general monograph 0125 (rule); organic-phase radiosynthesis assumed from isotope/compound class, no synthesis data confirming it -> GC residual solvents (preliminary); conventional nucleophilic 18F-fluorination assumed from isotope/compound class, no synthesis data confirming K222 use -> Kryptofix test (preliminary)

Tests listed by reference only. Monograph texts are copyrighted and are not reproduced here. How these are derived

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Notes

Added from reverse module search (stage 6); 3 article(s) with F-18. Compound class inferred from precursor name (not stated outright) -- PMID 31759313: 'Benzyl-14-(R,S)-tosyloxy-6-thiaheptadecanoate and methyl 16-bromo-4-thia-palmitate were used as precursors for the synthesis of [18F]FTHA and [18F]FTP, respectively.'.