Tracers / [18F]FMAU

[18F]FMAU

Also written as [18F]FMAU; [F-18]FMAU; FMAU
Radionuclide
F-18 t½ 109.77 min
Modality
PET
Production route
Stage
Syntheses indexed
5

What it is

Compound class
Radiolabelled pyrimidine nucleoside analogue (arabinofuranosyl-uracil derivative)
Target / mechanism
Thymidine kinase-mediated phosphorylation and incorporation into DNA (marker of DNA synthesis) PMID 12468521
Clinical application
Theranostic pair

Regulatory status

FDA
EMA (centralised)
Other approvals
Brand names

Clinical use

Typical injected activity
Uptake time

Reported in the literature. Not a dosing recommendation.

Published syntheses

ModuleCassettePurificationYield %RCP %Precursor / supplierSource
In-house / custom builtcustom manifoldHPLC+SPE28±7%
yes
uracil precursor23702795
2013 Appl Radiat Isot
1-(2′-deoxy-2′-[18F]fluoro-β-D-arabinofuranosyl)thymine (D-[18F]FMAU) was also synthesized on the system using the same protocol as for D-[18F]FAC — with a decay-corrected radiochemical yield of 28±7% (n=3)
ELIXYS FLEX/CHEM
Sofie Biosciences
vendor cassetteHPLC46 ± 1
yes
>99%2-O-(trifluoromethylsulfonyl)-1,3,5-tri-O-benzoyl-alpha-l-ribo-furanose and 5-methyl-2,4-bis[(trimethylsilyl)oxy]pyrimidine
ABX
23849185
2013 EJNMMI Res
an automated three-reactor radiosynthesizer (ELIXYS) — 46% ± 1% (n = 6) and 31% ± 5% (n = 6), respectively
HPLC20 ± 4%
yes
>99%2-deoxy-2-[(18)F]fluoro-1,3,5-tri-O-benzoyl-d-arabinofuranose22503457
2012 Nucl Med Biol
Microwave-assisted one-pot radiosynthesis of 2'-deoxy-2'-[18F]fluoro-5-methyl-1-β-d-arabinofuranosyluracil ([18F]-FMAU). — The overall radiochemical yield was 20 ± 4% (decay corrected, n=3).
22191612
2011 Curr Radiopharm
HPLC12±3%
yes
>99%21315275
2011 Nucl Med Biol
a fully automated synthesis of [(18)F]-FMAU based on a one reactor radiosynthesis module — [(18)F]-FMAU was obtained in 12±3% radiochemical yield (decay corrected overall yield based on [(18)F]-F(-), n=4)

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Quality control Preliminary — inferred from compound class

Ph. Eur. monograph
USP monograph
AppearancepHRCP HPLCRCP TLCHPLC UVRadionuclidic (HPGe)Half-lifeActivityEndotoxins (LAL)SterilityFilter integrity
How this set was arrived at. base set per Ph. Eur. general monograph 0125 (rule); organic-phase radiosynthesis assumed from isotope/compound class, no synthesis data confirming it -> GC residual solvents (preliminary); conventional nucleophilic 18F-fluorination assumed from isotope/compound class, no synthesis data confirming K222 use -> Kryptofix test (preliminary)

Tests listed by reference only. Monograph texts are copyrighted and are not reproduced here. How these are derived

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Notes

Added from reverse module search (stage 6); 4 article(s) with F-18.